I was just thinking of putting my own numbers in from my PSX memory card but can't find the locations. For a quick look, go into test, A.D.S. Mode, press button 1 once and it shows you character usage. You must finish one game for a character to be used (fastest thing is to lose and quit or continue).
My nvram is derived from the original ZiNc romset, tk2b. the nvram file was dumped and is simply called "eeprom". It works for all ver.b sets but not ver.a which saves differently. For a reference the file is up on http://tekkenzone.tripod.com/download/ - the MAME .nv file might be a little outdated so use the ZiNc one (tk2b.cfg) and rename it to fit MAME.
Here's a list of the first couple of characters (different from the above link):
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CHAR TOTAL 1P VS.
BAEK 3062 2806 256
PAUL 2352 2153 199
LAW 1703 1543 160
LEI 1318 1193 125
KING 1198 1089 109
NINA 1061 968 93
MIC 913 849 64
JUN 763 716 47
HEI 608 566 42
Maybe I should have tried the 1P number (2806 or 0AF6) instead of looking for the total.